A: The 1965 edition is Physical Methods in Inorganic Chemistry (430 pages), focusing specifically on inorganic chemistry. The 1977 edition is the expanded Physical Methods in Chemistry (660 pages), covering broader chemical applications.
| Chapter | Topics Covered | Key Concepts | | :--- | :--- | :--- | | 7 | Nuclear magnetic resonance (NMR) spectroscopy (elementary aspects) | Chemical shift, spin-spin coupling, integration, NMR-active nuclei | | 8 | Dynamic and Fourier transform NMR | NMR timescales, exchange processes, relaxation, FT-NMR principles | | 9 | Electron paramagnetic resonance (EPR) spectroscopy | g-values, hyperfine splitting, zero-field splitting, paramagnetic species | | 10 | Electronic structure and spectra of transition metal ions | Crystal field theory, ligand field theory, Tanabe-Sugano diagrams | | 11 | Magnetism | Diamagnetism, paramagnetism, Curie law, magnetic moments, Gouy balance | | 12 | NMR of paramagnetic substances in solution | Contact shifts, pseudocontact shifts, relaxation agents |
: Analysis of UV-Vis spectra, particularly for transition metal complexes. Magnetic Resonance A: The 1965 edition is Physical Methods in
While standard NMR texts focus on diamagnetic organic molecules, Drago addresses the unique challenges of inorganic NMR. This includes interpreting spectra shifted or broadened by unpaired electrons (isotropic shifts, contact shifts, and pseudocontact shifts), allowing chemists to extract structural data from complex coordination environments. 4. Vibrational Spectroscopy (IR and Raman)
-values, hyperfine coupling, and the zero-field splitting found in transition metal radicals and coordination complexes. 7. Mössbauer Spectroscopy A specialized technique focusing on iron ( ) and tin ( Magnetic Resonance While standard NMR texts focus on
. It is widely used by senior undergraduate and graduate students to bridge the gap between theoretical principles and practical laboratory applications. Google Books Availability and Access
I can provide legal reference links or summarize specific concepts from the text. Share public link Vibrational Spectroscopy (IR and Raman) -values
"Physical Methods in Inorganic Chemistry" by RS Drago is a seminal book that has been widely used by researchers and students in the field of inorganic chemistry. The book provides a comprehensive overview of the physical methods used in inorganic chemistry, including spectroscopy, magnetic properties, and electrochemical methods. It covers both the theoretical and practical aspects of these methods, making it an invaluable resource for those working in the field.